by rpavlis on Wed Aug 08, 2007 12:37 pm
Bleach is an aqueous solution of sodium hypochlorite. It typically is present to the extent of about 60 grams/litre or about 1M. This material is not stable except as a somewhat dilute solution. As water is removed from a solution of it it gradually undergoes disproportionation reaction to make sodium chloride and sodium chlorate, and some chlorine oxides (which are gases at room temperature.)
However, because it is a strong oxidising agent, it tends to react with a lot of things it contacts before anything else can happen.
Thus the answer is that it cannot stay around because it is too unstable.
Its advantage is, in fact, the fact that it is unstable. By the way, it is extremely dangerous to add ammonia to it, chloramine forms. Furthermore if acid be added nasty mixtures of elemental chlorine and chlorine oxides will form. Sodium hyposulphate or sodium sulphite are commonly used to destroy it.
Most disinfectants are toxic organic compounds like phenol and cresol. hypochlorite is cheap and decomposes completely on removal of the water, though there may be chlorate residues in some cases.